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(1,3-Dioxolan-2-ylethyl)zinc bromide 0.5 M in Tetrahydrofuran

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names：
(1,3-Dioxolan-2-ylethyl)zinc bromide
CAS號(hào)：
864501-59-7
MDL Number：
MF(分子式)： C5H9BrO2Zn MW(分子量)： 246
EINECS: Reaxys Number:
Pubchem ID: Brand:BIOFOUNT

(1,3-Dioxolan-2-ylethyl)zinc bromide 0.5 M in Tetrahydrofuran

貨品編碼	規(guī)格	純度	價(jià)格 (￥)	現(xiàn)價(jià)(￥)	特價(jià)(￥)	庫(kù)存描述	數(shù)量	總計(jì) (￥)
LSH53885-50mL	50mL	95%	￥ 3248.00	￥ 3248.00		Backorder	- +	￥ 0.00

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中文別名	(1,3-Dioxolan-2-ylethyl)zinc bromide 0.5 M in Tetrahydrofuran(864501-59-7)
英文別名	Bromo[2-(1,3-dioxolan-2-yl)ethyl]zinc:(864501-59-7)
CAS號(hào)	864501-59-7
Inchi	InChI=1S/C5H9O2.BrH.Zn/c1-2-5-6-3-4-7-5;;/h5H,1-4H2;1H;/q;;+1/p-1
InchiKey	MCHPKCUDPUMOJG-UHFFFAOYSA-M
分子式 Formula	C5H9BrO2Zn
分子量 Molecular Weight	246
溶解度Solubility
性狀
儲(chǔ)藏條件 Storage conditions	storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)

(1,3-Dioxolan-2-ylethyl)zinc bromide 0.5 M in Tetrahydrofuran(864501-59-7)實(shí)驗(yàn)注意事項(xiàng)：
1.實(shí)驗(yàn)前需戴好防護(hù)眼鏡，穿戴防護(hù)服和口罩，佩戴手套，避免與皮膚接觸。
2.實(shí)驗(yàn)過(guò)程中如遇到有毒或者刺激性物質(zhì)及有害物質(zhì)產(chǎn)生，必要時(shí)實(shí)驗(yàn)操作需要手套箱內(nèi)完成以免對(duì)實(shí)驗(yàn)人員造成傷害。
3.取樣品的移液槍頭需及時(shí)更換，必要時(shí)為避免交叉污染盡可能選擇濾芯吸頭。
4.稱量藥品時(shí)選用稱量紙，并無(wú)風(fēng)處取藥和稱量以免揚(yáng)撒，試劑的容器使用前務(wù)必確保干凈，并消毒。
5.取藥品時(shí)盡量采用多個(gè)藥勺分別使用，使用后清洗干凈后，烘干消毒存放。
6.實(shí)驗(yàn)后產(chǎn)生的廢棄物需分類(lèi)存儲(chǔ)，并交于專業(yè)生物廢氣物處理公司處理，以免造成環(huán)境污染。
Experimental considerations:
1. Wear protective glasses, protective clothing and masks, gloves, and avoid contact with the skin during the experiment.
2. The waste generated after the experiment needs to be stored separately, and handed over to a professional biological waste gas treatment company to avoid environmental pollution.

產(chǎn)品說(shuō)明	(1,3-Dioxolan-2-ylethyl)zinc bromide 0.5 M in Tetrahydrofuran(864501-59-7):僅做科學(xué)研究以及化學(xué)合成中間體使用,864501-59-7其他參數(shù)見(jiàn)主頁(yè)
Introduction	Bromo[2-(1,3-dioxolan-2-yl)ethyl]zinc:(864501-59-7) used for scientific research and chemical synthesis intermediates
Application1
Application2
Application3

警示圖
危險(xiǎn)性	warning
危險(xiǎn)性警示	No data available
安全聲明	H303+H313+H333
安全防護(hù)	P264+P280+P305+P351+P338+P337+P313
備注	實(shí)驗(yàn)過(guò)程中防止吸入、食入，做好安全防護(hù)

Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 51..Couplings of Alkylzinc Reagents (Negishi Reaction) Mediated by Nickel and Palladium,Science of SynthesisKocienski, Philip; Komsta, Zofia, Synfacts 2008, 907.Formal Synthesis of Fluvirucinine A1,Synfacts[DOI: 10.1055s-2008-1077990]

Li, L.; Biscoe, M. R., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 799..Coupling with Aryl Iodides,Science of SynthesisLi, L.; Biscoe, M. R., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 822..Coupling with Alkenyl Electrophiles,Science of SynthesisLi, L.; Biscoe, M. R., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 813..Coupling with Primary Alkyl Bromides,Science of SynthesisLi, L.; Biscoe, M. R., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 808..

Hiyama, T..Reaction of Organometallic Reagents with Secondary Organic Halides,Science of Synthesis: Stereoselective Synthesis, (2011) 3, 575.

Coupling with Aryl Sulfonates,Science of SynthesisLi, L.; Biscoe, M. R., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 819..Coupling with Benzylic Halides,Science of SynthesisLi, L.; Biscoe, M. R., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 817..Coupling with Unactivated Secondary Alkyl Halides,Science of SynthesisLautens, Mark; Loh, Charles C. J., Synfacts 2015, 11, 826.Asymmetric Iridium-Catalyzed Allylation Utilizing Organozinc Bromides,Synfacts[DOI: 10.1055s-0034-1381188]

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