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Jimenezin

NMR下載 COA and HPLC MSDS下載
names：
(S)-3-((2R,13R)-13-((2R,5R)-5-((2S,5R,6S)-6-decyl-5-hydroxytetrahydro-2H-pyran-2-yl)tetrahydrofuran-2-yl)-2,13-dihydroxytridecyl)-5-methylfuran-2(5H)-one
CAS號(hào)：
204185-17-1
MDL Number：
MF(分子式)： C37H66O7 MW(分子量)： 622.92
EINECS: Reaxys Number:
Pubchem ID: Brand:BIOFOUNT

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中文別名	Jimenezin
英文別名	Jimenezin;
CAS號(hào)	204185-17-1
Inchi	InChI=1S/C37H66O7/c1-3-4-5-6-7-12-15-18-21-33-32(40)22-23-35(43-33)36-25-24-34(44-36)31(39)20-17-14-11-9-8-10-13-16-19-30(38)27-29-26-28(2)42-37(29)41/h26,28,30-36,38-40H,3-25,27H2,1-2H3/t28-,30+,31+,32+,33-,34+,35-,36+/m0/s1
InchiKey	MAHVNJPZHYFHHE-IMEDPYHGSA-N
分子式 Formula	C37H66O7
分子量 Molecular Weight	622.92
溶解度Solubility
性狀	Solid powder
儲(chǔ)藏條件 Storage conditions	Dry, dark and store at 0-4℃ for short term (days to weeks) or -20℃ for long term (Store correctly 2-3years).

產(chǎn)品說明	Jimenezin(CAS:204185-17-1):僅限應(yīng)用于工業(yè)或者科學(xué)研究過程中非醫(yī)療目的，不應(yīng)用于人類或動(dòng)物的臨床診斷以及治過程療，該產(chǎn)品非藥用，非食用。
Introduction	Jimenezin is a member of the class of compounds known as annonaceous acetogenins. Annonaceous acetogenins are waxy derivatives of fatty acids (usually C32 or C34), containing a terminal carboxylic acid combined with a 2-propanol unit at the C-2 position to form a methyl- substituted alpha,beta-unsaturated-gamma-lactone. One of their interesting structural features is a single, adjacent, or nonadjacent tetrahydrofuran (THF) or tetrahydropyran (THP) system with one or two flanking hydroxyl group(s) at the center of a long hydrocarbon chain. Jimenezin is practically insoluble (in water) and a very weakly acidic compound (based on its pKa). Jimenezin can be found in alcoholic beverages and fruits, which makes jimenezin a potential biomarker for the consumption of these food products. Jimenezin is found in alcoholic beverages. Jimenezin is a constituent of the seeds of Rollinia mucosa (biriba).
Application1
Application2
Application3

警示圖
危險(xiǎn)性	Warning
危險(xiǎn)性警示
安全聲明
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[1]Matsui Y, Takeuchi T, Kumamoto-Yonezawa Y, Takemura M, Sugawara F, Yoshida H, Mizushina Y. The relationship between the molecular structure of natural acetogenins and their inhibitory activities which affect DNA polymerase, DNA topoisomerase and human cancer cell growth. Exp Ther Med. 2010 Jan;1(1):19-26. Epub 2010 Jan [1]PubMed PMID: 23136587; PubMed Central PMCID: PMC3490394.

[2]Takahashi S, Yonezawa Y, Kubota A, Ogawa N, Maeda K, Koshino H, Nakata T, Yoshida H, Mizushina Y. Pyranicin, a non-classical annonaceous acetogenin, is a potent inhibitor of DNA polymerase, topoisomerase and human cancer cell growth. Int J Oncol. 2008 Feb;32(2):451-8. PubMed PMID: 18202768.

[3] Bandur NG, Brückner D, Hoffmann RW, Koert U. Total synthesis of jimenezin via an intramolecular allylboration. Org Lett. 2006 Aug 17;8(17):3829-31. PubMed PMID: 16898828.

[4] Takahashi S, Maeda K, Hirota S, Nakata T. Total synthesis of a new cytotoxic acetogenin, jimenezin, and the revised structure. Org Lett. 1999 Dec 16;1(12):2025-8. PubMed PMID: 10905863.

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