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pNNP

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names：
4-nitrophenyl dihydrogen phosphate
CAS號(hào)：
330-13-2
MDL Number：
MF(分子式)： C6H6NO6P MW(分子量)： 219.08
EINECS: Reaxys Number:
Pubchem ID: Brand:BIOFOUNT

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中文別名	4-nitrophenyl dihydrogen phosphate
英文別名	pNNP; p-NNP; p NNP; p-Nitrophenyl phosphate;
CAS號(hào)	330-13-2
Inchi	InChI=1S/C6H6NO6P/c8-7(9)5-1-3-6(4-2-5)13-14(10,11)12/h1-4H,(H2,10,11,12)
InchiKey	XZKIHKMTEMTJQX-UHFFFAOYSA-N
分子式 Formula	C6H6NO6P
分子量 Molecular Weight	219.08
溶解度Solubility
性狀	Solid powder
儲(chǔ)藏條件 Storage conditions	Dry, dark and store at 0-4℃ for short term (days to weeks) or -20℃ for long term (Store correctly 2-3years).

產(chǎn)品說(shuō)明	pNNP(CAS:330-13-2):僅限應(yīng)用于工業(yè)或者科學(xué)研究過(guò)程中非醫(yī)療目的，不應(yīng)用于人類或動(dòng)物的臨床診斷以及治過(guò)程療，該產(chǎn)品非藥用，非食用。
Introduction	pNNP is used as a substrate instead of phosphorylated proteins in the PP2C assay.
Application1
Application2
Application3

警示圖
危險(xiǎn)性	Warning
危險(xiǎn)性警示
安全聲明
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[1]Demmans KZ, Seo CSG, Lough AJ, Morris RH. From imine to amine: an unexpected left turn. Cis-β iron(ii) PNNP' precatalysts for the asymmetric transfer hydrogenation of acetophenone. Chem Sci. 2017 Sep 1;8(9):6531-654[1]doi: 10.1039/c7sc02558k. Epub 2017 Jul 14. PubMed PMID: 28989679; PubMed Central PMCID: PMC5627452.

[2]Li YY, Yu SL, Shen WY, Gao JX. Iron-, Cobalt-, and Nickel-Catalyzed Asymmetric Transfer Hydrogenation and Asymmetric Hydrogenation of Ketones. Acc Chem Res. 2015 Sep 15;48(9):2587-98. doi: 10.1021/acs.accounts.5b00043. Epub 2015 Aug 24. PubMed PMID: 26301426.

[3] Kumar S, Mani G, Dutta D, Mishra S. Structural diversity of copper(I) complexes formed by pyrrole- and dipyrrolylmethane-based diphosphine ligands with cu-X···HN hydrogen bonds. Inorg Chem. 2014 Jan 21;53(2):700-9. doi: 10.1021/ic402253y. Epub 2014 Jan 3. PubMed PMID: 24392950.

[4] Kumar S, Mani G, Mondal S, Chattaraj PK. Pyrrole-based new diphosphines: Pd and Ni complexes bearing the PNP pincer ligand. Inorg Chem. 2012 Nov 19;51(22):12527-39. doi: 10.1021/ic301967r. Epub 2012 Nov 8. PubMed PMID: 23137009.

[5] Mikhailine AA, Maishan MI, Morris RH. Asymmetric transfer hydrogenation of ketimines using well-defined iron(II)-based precatalysts containing a PNNP ligand. Org Lett. 2012 Sep 7;14(17):4638-41. doi: 10.1021/ol302079q. Epub 2012 Aug 27. PubMed PMID: 22924839.

6: Mikhailine AA, Maishan MI, Lough AJ, Morris RH. The mechanism of efficient asymmetric transfer hydrogenation of acetophenone using an iron(II) complex containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 ligand: partial ligand reduction is the key. J Am Chem Soc. 2012 Jul 25;134(29):12266-80. doi: 10.1021/ja304814s. Epub 2012 Jul 13. PubMed PMID: 22793266.7: Sonnenberg JF, Coombs N, Dube PA, Morris RH. Iron nanoparticles catalyzing the asymmetric transfer hydrogenation of ketones. J Am Chem Soc. 2012 Apr 4;134(13):5893-9. doi: 10.1021/ja211658t. Epub 2012 Mar 26. PubMed PMID: 22448656.8: Schotes C, Althaus M, Aardoom R, Mezzetti A. Asymmetric Diels-Alder and Ficini reactions with alkylidene β-ketoesters catalyzed by chiral ruthenium PNNP complexes: mechanistic insight. J Am Chem Soc. 2012 Jan 18;134(2):1331-43. doi: 10.1021/ja210372u. Epub 2012 Jan 6. PubMed PMID: 22191539.9: Schotes C, Mezzetti A. Enantioselective Diels-Alder reactions of unsaturated beta-ketoesters catalyzed by chiral ruthenium PNNP complexes. Chimia (Aarau). 2011;65(4):231-4. PubMed PMID: 21678768.10: Lagaditis PO, Lough AJ, Morris RH. Low-valent ene-amido iron complexes for the asymmetric transfer hydrogenation of acetophenone without base. J Am Chem Soc. 2011 Jun 29;133(25):9662-5. doi: 10.1021/ja202375y. Epub 2011 Jun 7. PubMed PMID: 21627152.1

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